Covalent Bond

A covalent bond is formed when two atoms exchange one or more pairs of electrons. Both the atomic nuclei of the shared atom together attract these electrons. When the difference between the electronegativities of two atoms is too small for an electron transfer to take place to create ions, a covalent bond is formed. Bonding electrons are collectively referred to as the electrons that are present between the two nuclei. The “bond” that holds the atoms in molecular units together is the bound pair.

What is Covalent Bond?

A covalent bond is formed when electrons from both participating atoms are shared equally. The pair of electrons involved in this type of bonding is known as a shared pair or bonding pair. 

Molecular bonds are another name for covalent bonds. The sharing of bonding pairs will ensure that the atoms achieve stability in their outer shell, similar to noble gas atoms.

Elements with extremely high ionization energies are incapable of transferring electrons, and elements with extremely low electron affinity are incapable of absorbing electrons. The atoms of such elements tend to share electrons with atoms of other elements or atoms of the same element in such a way that both atoms achieve octet configuration in their respective valence shells and thus achieve stability. A covalent Bond refers to such an association formed by the sharing of electron pairs among different or similar kinds.

Covalent Bonding in Carbon Atom

A carbon atom has 4 electrons in its outermost orbit and it can logically have 3 possible ways of sharing its electrons.

A carbon atom can gain 4 electrons to become C^4-  but it is not possible because it will be tough for 6 protons to hold 10 electrons and so the atom will become unstable.

A carbon can lose 4 electrons to become C⁴⁺ but it would require a large amount of energy to remove out 4 electrons which again is not possible and the C⁴⁺ would have only 2 electrons held by the proton, which again is unstable.

Thus carbon can not gain or donate electrons, so to complete its octet carbon atom can share all four electrons and form four covalent bonds.

The image given below shows the Bonding in Carbon atoms.

Covalent Bond Examples 

Here some important examples of covalent bonds are discussed in brief:

Covalent Bond in Water

Covalent bonds hold the hydrogen and oxygen atoms that makeup water molecules together. The incomplete outer shells of the hydrogen and oxygen atoms are where the hydrogen electron from the hydrogen spends the majority of its time. Two electrons (one from each hydrogen atom) are required to completely occupy the outer shell of oxygen, which contains six electrons but would be more stable with eight. 

This results in the well-known formula H₂O. Both elements become more stable as a result of the sharing of electrons, which fill their respective outer shells.

The image given below shows Covalent Bond in Water.

Some Important Carbon Compounds with Covalent Bonds

Methane 

The outermost shell of carbon contains four electrons, and it requires four more to fill it. Each hydrogen atom contributes one toward these four, producing a stable outer shell of eight electrons. Despite not having the same electronegativity, hydrogen, and carbon are similar, and nonpolar bonds result. 

The outermost shell of the hydrogen atoms, which is full when it has two electrons, requires one electron for each atom. These substances combine to form a nonpolar covalent molecule by evenly distributing their electrons across the hydrogen and carbon atoms.

Carbon Dioxide

Carbon Dioxide has two covalent bonds between carbon and oxygen atoms and its structure can easily be made using Lewis Dot methods. Carbon has four electrons in its outermost shell whereas oxygen has six electrons in its outermost shell, now carbon needs four electrons and oxygen needs two electrons to complete their octet. So carbon shares two electrons with both the oxygen atoms and hence all three atoms (One carbon atom and two oxygen atoms) achieve their stable configuration and thus, CO₂ is formed.

Properties of Covalent Bond

If sharing a single electron pair between atoms does not satisfy an atom’s normal valence, the atoms may share more than one electron pair between them. Covalent bonds have the following properties:

• The formation of new electrons is not the result of covalent bonding. The bond only connects them.
• They are extremely strong chemical bonds that exist between atoms.
• Covalent bonds rarely break on their own after they are formed.
• Covalent bonds are directional in the sense that the atoms that are bonded have distinct orientations relative to one another.
• Most covalently bonded compounds have relatively low melting and boiling points.
• Compounds with covalent bonds usually have lower enthalpies of vaporization and fusion.
• Compounds formed by covalent bonding don’t conduct electricity due to the lack of free electrons.
• Covalent compounds are not soluble in water.

What is the Octet Rule?

Except for noble gases, all atoms have fewer than eight electrons in their valence shell which are called valence electrons. In other words, these atoms’ valence shells do not have stable configurations. As a result, they combine with one another or with other atoms to form stable electronic configurations.

The tendency of atoms of different elements to achieve a stable configuration of eight electrons in their valence shells is the cause of chemical combination, and the principle of achieving a maximum of eight electrons in an atom’s valence shell is known as the octet rule.

Conditions for Writing the Lewis Dot Structures

Lewis Dot structure can easily explain the formation of the covalent bonds between two molecules. Some points we must remember for drawing Lewis Dot Structures are,

• Covalent bonds are formed only when the electron pair is shared between two atoms.
• Two electrons or one electron pair constitute a single covalent bond in which each atom shares one electron.
• The sharing between atoms occurs to satisfy the Octet state of the Valence Shell. Octet rule states that an element’s stability is achieved only when it has 8 electrons in its outermost shell (except for the hydrogen atom which achieves its stability with 2 electrons in its outermost shell)

For Example, In the formation of an H₂O molecule Hydrogen atom has one electron in its outermost shell and oxygen has six electrons in its outermost shell when two electrons of oxygen form a bond with two hydrogen atoms its octet is completed. Similarly, the stability of Hydrogen atoms is also achieved.

Types of Covalent Bonds

Depending upon the number of shared electron pairs, the covalent bond can be classified into 

• Single Covalent Bonds
• Double Covalent Bonds
• Triple Covalent Bonds.

Single Bonds

When only one pair of electrons is shared by the two participating atoms, a single bond is formed. It is denoted by a single dash (-). Despite having a lower density and being weaker than a double or triple bond, this type of covalent bond is the most stable. 

For example, an HCl molecule contains one Hydrogen atom with one valence electron and one Chlorine atom with seven valence electrons. In this case, hydrogen and chlorine form a single bond by sharing one electron.

Double Bonds

When two pairs of electrons are shared by two participating atoms, a double bond is formed. It’s denoted by two dashes (=). Although double covalent bonds are much stronger than single bonds, they are also less stable.

One carbon atom has six valence electrons and two oxygen atoms have four valence electrons in a carbon dioxide molecule, for example, Carbon shares two of its valence electrons with one oxygen atom and two with another oxygen atom to complete its octet. Because each oxygen atom shares two electrons with carbon, CO₂ contains two double bonds.;

Oxygen-Molecule: Each oxygen atom in the formation of the oxygen molecule has six electrons in its valence shell. To complete their octet, each atom requires two more electrons. As a result, the atoms share two electrons to form the oxygen molecule. Because two electron pairs are shared, the two oxygen atoms form a double bond.

Triple Bond

When three pairs of electrons are shared by two participating atoms, a triple bond is formed. Triple covalent bonds are the least stable type of covalent bond and are represented by three dashes. 

In the formation of a nitrogen molecule, for example, each nitrogen atom with five valence electrons contributes three electrons to form three electron pairs for sharing. As a result, a triple bond forms between the two nitrogen atoms.

Polarization of Covalent Bonds

Covalent (sigma) Bonds also show some properties of electrovalent bonds this is achieved as the electron cloud between the two atoms in the sigma bond shifts towards one atom due to the difference in their electronegativity and the atom which attracts the electron cloud attains a partial negative charge and the other atom achieved a partial negative charge. Thus, due to these charges polarization happens and this results in the Polarization of Covalent Bonds

For example, the sigma (covalent bond) in HCl is a polar covalent bond as Chlorine(Cl) has a higher electronegativity than Hydrogen(H). So the electron charge shifts towards Chlorine and it attains a partial negative charge. Similarly, Hydrogen attains a partial positive charge.

Polar Covalent Bond

This type of covalent bond exists when the electronegativity of combining atoms differs, resulting in unequal electron sharing. Electrons will be drawn to more electronegative atoms. The atoms’ electronegative difference is greater than zero but less than 2. 

As a result, the shared electron pair will be closer to that atom. For example, consider molecules that form hydrogen bonds due to an unbalanced electrostatic potential. The hydrogen atom in this case interacts with electronegative fluorine, hydrogen, or oxygen.

Nonpolar Covalent Bond

This type of covalent bond is formed when two atoms share an equal number of electrons. The difference in electronegativity between two atoms is zero. 

It occurs whenever the atoms combined have a similar electron affinity. Nonpolar Covalent Bonds, for example, can be found in gas molecules such as hydrogen gas, nitrogen gas, and so on.

Coordinate Covalent Bond

Coordinated or Dative Covalent Bond, this type of bond occurs when one of the atoms in the bond provides electrons for sharing. This is accomplished through the reaction of ammonia and boron trifluoride. Nitrogen has two free electrons, whereas boron lacks electrons. They complete their last shell with eight electrons by combining nitrogen and boron.

Difference between Ionic and Covalent Bond

The major differences between Ionic Bonds and Covalent Bonds are discussed in the table given below,

Covalent Bond	Ionic Bond
A covalent bond is formed when two similar electronegative nonmetals come together.	This type of bond is formed when a metal and a non-metal combine.
Bonds formed by covalent bonding have a distinct shape.	No definite shape
Covalent Bond has low melting and boiling point.	While Ionic Bond has high melting and boiling point.
They have low polarity.	They have high polarity.
The compounds formed by the covalent bond are more flammable.	The compounds formed by the ionic bond are less flammable.
They are in the liquid or gaseous state at room temperature.	They are in a solid state.
e.g. HCl, etc.	e.g. NaCl, etc.

FAQs on Covalent Bonds

Q1: What are covalent bonds?

Answer:

The bonds formed by the sharing of atoms between two elements are called covalent bonds. Covalent bonds are formed to complete the octet of the outer shell of the atom.

Q2: How are covalent bonds formed?

Answer:

covalent bonds are formed by sharing of electrons between two atoms. On the basis of the number of electrons shared covalent bonds are of three types.

• Single Covalent Bond: If one electron pair is shared between two elements they form a single covalent bond.
• Double Covalent Bond: If two electron pairs are shared between two elements they form a double covalent bond.
• Triple Covalent Bond: If three electron pairs are shared between two elements they form a triple covalent bond.

Q3: What are polar and nonpolar covalent bonds?

Answer:

Polar Covalent Bond: For any covalently bonded molecule if the elements combined have huge differences in their electronegativity the electron charge density of the shared pair of electrons shifts towards the more electronegative elements and the bond behaves as electrovalent bonds these bonds are called a polar covalent bond.

Non-Polar Covalent Bond: For any covalently bonded molecule if the elements combined have negligible differences in their electronegativity these bonds are called non-polar covalent bonds.

Q4: How many covalent bonds are in Cyclohexane?

Answer:

Cyclohexane as the name suggests is a cyclic compound which is formed by the covalent bonds between Carbon and Hydrogen. Cyclohexane has 6 Carbon and 12 Hydrogen atoms. Cyclohexane has total 18 covalent bonds.

Q5: How many covalent bonds are present in Ethane?

Answer:

Ethane is the most common organic compound which is formed by 2 Carbon and 6 Hydrogen atoms. Ethane has 7 covalent bonds.

Q6: What are the total number of covalent bonds in CH₄ (methane)?

Answer:

The simplest organic compound Methane has a total of four (4) covalent bonds between carbon and hydrogen atoms.

Q7: Which molecule contains both polar and nonpolar covalent bonds?

Answer:

H₂O₂ molecule contains both polar and non-polar bonds. It contains a polar covalent bond between Oxygen and Hydrogen atoms and a non-polar covalent bond between the two oxygen atoms.