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Aluminum Iodide Formula – Structure, Properties, Uses, Sample Questions

Last Updated : 20 Dec, 2023
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Aluminum Iodide is a simple chemical created when aluminum combines with iodine, and it is naturally white or yellow in color. Aluminum iodide is a strong Lewis base, which means it has an empty orbital that can take an electron pair from another Lewis base to generate a Lewis product. It was employed to disrupt chemical bonds between compounds such as C-O and N-O. Aluminum iodide is used as an electrolyte additive in lithium-ion batteries.

Aluminum iodide is a compound made up of solely aluminum and iodine.  It is an ionic molecule that acts as a catalyst in certain organic processes. Furthermore, we obtain a hexahydrate by reacting metallic aluminum or aluminum hydroxide with hydrogen iodine or hydroiodic acid. It is a strong Lewis acid and it will absorb water from the atmosphere.
It also deoxygenates epoxides and cleaves aryl ethers. 

Aluminum Iodide formula

It is dimeric (comprised of two identical simpler molecules), similar to AlBr3, and is constituted of Al2I6.  The monomeric and dimeric versions of its structure are defined by the gas phase. Furthermore, AlI3 is a trigonal planar monomer, and the bridging dimer Al2I6 is identical to Al2CL6 and Al2Br6. Both elements occur separately in nature, and aluminum iodide develops under particular circumstances in laboratories and industry. Iodine occurs as a molecule I2 and aluminum exists freely in atomic form. 

Aluminum iodide has the chemical formula AlI3. 

 

Preparation for Aluminum iodide 

Iodine is a member of the halogen family, which consists of highly reactive nonmetals. However, as it is a diatomic element, it is extremely reactive and considerably more stable in molecule form. This results in I2. since aluminum occurs in atomic form, the reaction between aluminum and iodine is,

Al + I2 ⇢ AlI3 

The reaction starts with two iodine atoms and concludes with three iodine atoms. This occurs because an aluminum atom must lose one electron or receive three electrons in order to complete its outer shell electrons. Similarly, iodine must either gain or lose 1 electron to complete its outer shell. As a result, three iodine atoms are required to complete aluminum’s outer shell. 

Physical properties of Aluminum iodide 

  • It has a colorless powder with a density of 3.98 g/cm3.
  • It has a melting point of 189.4°C and a boiling point of 360°C.
  • The molar mass of aluminium iodide is 407.69 g/mol.
  • It dissolves in water, ethanol, diethyl ether, carbon disulfide, pyridine, and sulfur dioxide. 

Chemical Properties of Aluminum iodide 

  • It is an ionic compound that is used as a catalyst (a substance added to speed up the process) in some organic processes and as a spray for treating animal stalls.
  • It also generates a lot of heat, indicating that it is exothermic, which is why scientists and industries conduct it in a particular heat-resistant container and a fume hood.
  • When iodine reacts with aluminum in the presence of water, the purple vapor is formed.  

Uses of Aluminium Iodide 

  • We commonly use it as an animal stall cleanser due to the general fact its vapor works.
  • Its treatment destroys microorganisms that cause respiratory diseases on the farm.
  • In organic chemistry, this can act as a catalyst, speeding up the reaction between elements or compounds.
  • It also breaks carbon-oxygen and nitrogen-oxygen bonds.
  • It also eliminates the oxygen atom from epoxides. 

Sample Questions 

Question 1: Is aluminum iodide a liquid or a gas?

Answer: 

Aluminium iodide is a gas because when Powdered aluminium is mixed with iodine in a heat-resistant container to start the reaction. The purple vapour we explained previously is formed when a few drops of water are added. The heat generated by the reaction leads the iodine to sublime, or change from a solid to a gas. 

Question 2: Is aluminum iodide poisonous?

Answer: 

Inhaling vapours or ingesting them might be fatal. Fine aluminium powders can combine with air to generate an explosive combination. Aluminum iodide, the reaction product, reacts aggressively with water. When heated, aluminium iodide emits a flammable vapour that, when combined with air and ignited, can explode and is corrosive to all bodily tissue. 

Question 3: Is the structure of aluminum iodide ionic or covalent?

Answer: 

Aluminum iodide is an ionic compound having one aluminium ion for every three iodide ions. The aluminium ion has a charge of +3, while the iodide ion has a charge of -1. 

Question 4: What exactly are iodide ions?

Answer: 

The ion I is an iodide ion. Iodides are compounds that contain iodine at formal oxidation state 1. Iodide is most often encountered in everyday life as a component of iodized salt. 

Question 5: When aluminum interacts with iodine, what happens?

Answer: 

Drops of water can be used to start the oxidation of finely scattered aluminium with iodine. Excess iodine vaporize, forming a deep violet vapour, as the reaction becomes strongly exothermic. 

Question 6: What is aluminum iodide powder, and how does it work?

Answer: 

Aluminium iodide is a chemical compound made up of the elements aluminium and iodine. The term always refers to a compound with the formula AlI3 that is produced by the reaction of aluminium with iodine or by the action of HI on Al metal. 

Question 7: Is aluminum iodide salt or a compound?

Answer: 

It is from binary compound group and inorganic Lewis acid, a specific sort of chemical capable of receiving an electron pair. Aluminum iodide, like other types of aluminium compounds, may absorb water from the air. It’s often referred to as aluminium salt or hydroiodic acid. 


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